top of page

The evaporation of complex fluids such as colloidal dispersions or polymer solutions is an elegant route to control the patterns of solutes on a solid surface. In most drying drop problems, a liquid drop containing a dispersed material is transformed into a dense or porous deposit of solids that finds potential application in many growing fields related to ink-jet printing, paints, functional coatings, and nanoparticle-based electronic devices. So far, the evaporation of particle-laden dispersion is mostly studied in the sessile configuration (i.e., drop on a horizontal flat substrate) and the commonly observed feature is the formation of a "coffee-ring" deposit in which most of the particles are deposited at the three-phase contact line. The mechanism of formation of such deposit pattern is known to form as a result of an outward capillary flow originating due to the pinning of the droplet and non-uniform evaporative flux along the surface of the drop.
 
Our study mainly focused on drying a colloidal dispersion to control the deposit patterns on the substrate. The combined effect of substrate orientation and wettability, the influence of configuration of drying dispersion such as sphere-on-plate, and the dispersion dried between two parallel plates were explored to control the final morphology of the dried deposit patterns on the substrates.

The drying of particle-laden dispersion on solid surfaces that results in the particulate film often exhibits cracks, similar to those commonly observed in the dried mud and old paintings. Although these cracks are unacceptable in many applications pertaining to coatings. The periodic cracks formed in a controlled manner find potential application as a lithography template for fabricating nano and micro-channels (for nano and micro-fluidic applications) and in optical grafting.

Colloidal Silica Particle

 Hematite Ellipsoidal Particles

Supra-colloidal structured assembly of colloids with controlled size, shape, and morphology has a wide range of applications in different fields, such as photonics, food and agriculture industry, catalysis, pharmaceuticals, and in paints or coatings. We explore the influence of the shape of constituent particles in the colloidal dispersion on the microstructural features of the self-assembled micro-granules through a controlled spray drying process.

My research interest include the fundamental understanding of freezing dispersion or ice-templating in general. Freezing is a versatile method to create macroporous materials in which the solvent crystal is used as template to control the macroporosity in the materials. This technique has been widely used in the ceramic community to make macroporous structures and in recent time it has been also used to prepare self-assembled structures of colloids and particle-polymer hybrids. The main advantages of this ice-templating method are the relatively limited equipment costs and simplicity of the process, compared to the other synthesis process of macroporous materials that are reported in the literature.

bottom of page